If you are trying to access the SMART information from a USB drive, then the USB controller for the USB Adapter, drive dock, or enclosure must allow the SMART communication to pass from the OS/app to the physical drive, but unfortunately many USB controllers on the adapters/docks/enclosures don't allow this to happen.
Plus with an NVMe based SSD, it may not support the traditional SMART interface to access the SMART information on the SSD. While some NVMe SSDs may have the older style access, most NVMe SSDs now have a new method of accessing the SSD's SMART health information. On Linux, this requires using a special new NVMe utility to access an NVMe SSD's SMART information and as far as I know can only be done through the command line. The only way to possibly check the health of the external NVMe SSD may be by using a Linux system or boot disk as suggested, but the GSmartControl app may not work for this purpose as it may require using the "nvme" command line utility which can be a bit tricky to use. If you are familiar with the command line, then I can give you some hints on how to attempt to check the NVMe USB SSD's health using Linux, but it may require you to do a little thinking & interpreting to actually identify the correct drive identifier for the SSD you want to check.
macOS has never really supported using SMART health information except to alert the user if a drive has a SMART health attribute reach a failure state which is quite rare since a hard drive rarely makes it that far before the drive issues make it impossible to boot the computer (I've only seen it happen two or three times on macOS, but I've replaced hundreds of bad hard drives that never had an macOS SMART alert issued). Sometimes the Apple Diagnostics may check the SMART attributes/health, but not to the necessary level of detail needed to catch most drive failures. It is unfortunate operating systems and drive vendors and even the makers of adapters/docks/enclosures do not properly implement or allow for access to a drive's SMART health information.