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Once Monterey became available in the Mac App Store, Big Sur disappeared. You can upgrade your 2019 iMac to Big Sur 11.6.1 by visiting the How to get old versions of macOS, using strictly the Safari browser, and then follow the provided link on that site to Big Sur in the Mac App Store. It will download to your /Applications folder from where you can perform the upgrade.
Since you appear to be coming from High Sierra, you should realize that no 32-bit applications are supported on Big Sur, and you can get a list of those by running the free Go64 application. You should also check that your printer/scanner vendors still provide Big Sur compatible device drivers (released in 2021), which you will need to install, or if your networkable printer is supported by Apple's built-in AirPrint solution. If it is, then you won't need vendor drivers. And finally, if applicable, your Office 2011 for Mac license and applications are unsupported on Big Sur, and will require a new license and binaries.
Recommend that you perform a Time Machine backup prior to the Big Sur upgrade, and then do not use the same TM drive for any Big Sur backups.