I just purchased this new Mac but no instructions came with it. Where can I get a hardcopy?

Instructions to do what?

Maybe this is what you are looking for: Move your content to a new Mac - Apple Support

Or maybe this: Virtual Session: Intro to Mac - Apple

Or maybe this: Mac tips for Windows switchers - Apple Support

In addition to the above, macOS also has built in links to support resources.

Click Apple menu () > About This Mac > Support tab. There you'll find clickable buttons for

macOS Help, the User Manual for your computer and additional macOS Support.

EDIT - Hard copies are not available, but everything is available on line.

Also, there are many books available on the subject. For example

Mac for Seniors: Monterey Edition - amazon.com

and

macOS Monterey for Dummies - amazon.com

If you google search the subject you'll find piles of books. 🙂

and in addition to the excellent resources already provided, perusing these forums is a good way to learn the many things your mac can do and what you can do with it. rarely does a day go by where i don't learn something new here.

In Finder >> Help and refer to image below

Alas, there is no "missing manual" for Monterey, but there is one for Catalina:

https://www.oreilly.com/missingmanuals/library.html