Watch band irritating skin the band for another material?
May I exchange the band for another material?
Apple Watch Series 7
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If you bought it directly from Apple, you have 14 calendar days to return an item from the date you received it. For more info see the 'Exchange an item' section in:
Returns & Refunds - Shopping Help - Apple
Otherwise it depends on the refund/exchange policy of the store you bought it from.