Are you saying you don't see the orange icon labeled "EFI" when hold the Option key immediately after the startup chime while the Knoppix USB stick is connected?
Or were you able to select the orange icon labeled "EFI" to begin booting Knoppix and it ends up with a blue screen? If you are able to do this, then lets try to force Knoppix to boot to the command line instead of the graphical desktop environment. I have seen Knoppix fail to boot to the desktop on systems with GPU issues.
Trying to force Knoppix to boot to the command line is a little tricky since you need to type something on the screen without being able to see what you are typing. Once you Option Boot the Knoppix USB stick, wait about 10 or 15 seconds, then press the F2 key. Then type the following all in lower case (make sure there is at least one space before the "2"...I put several just to accentuate the spacing so it is seen easily):
knoppix64 2
Press the "Return" key at the end of the line to execute the command. You may not see anything happen for a little bit, but hopefully you will at some point see a boot log or the command prompt.
If Knoppix boots to the command line, then you can issue the following command to list the connected drives (make sure there are no other external devices connected except for the Knoppix USB stick when booting Knoppix). We need to verify the drive identifier for the internal Mac drive.
sudo lsblk -f | grep -i sd
This should just display the internal and external drives. If there is only one internal drive and the Knoppix USB stick, then you will (in theory) just see two different drives listed identified by "sda" and "sdb" (there will be items linked from them for each partition on the respective drive designated by a trailing number -- the numbers are irrelevant for our purposes). One of these should be clearly listed as "Knoppix" while the other one may or may not show as Mac related. We need the drive identifier for the Mac drive which I believe will be designated as "sda", but it has been a while since I've done this myself.
Use the drive identifier for the Mac drive (or the drive identifier which is not listed as Knoppix) in the following command. If the Mac drive is instead associated with the "sdb" entries, then replace "sda" in the following command with "sdb" or whatever drive identifier is associated with the Mac drive.
sudo smartctl -a -s on /dev/sda | less
When you run this command, hopefully it will show the health report for the internal Mac drive. The " | less" part of the command actually will stop the output from scrolling off the screen. Just use the up & down arrow keys to scroll up & down the report so you can take a pictures of it to post here. Once you scroll to the end of the report and have taken the pictures and are done, you can just press the "q" key (lower case "Q"). You will be returned to the command prompt. If there is an error message or nothing is shown, then you may have used the wrong drive identifier in the command (you may still need to press "q" to get back to the command line).
Then just type the following to power off the Mac:
sudo shutdown -h now