Not easy because the network volume may come back in under a different name.
It also is very slow because how Photos works, is it manages all the files as an XML file mapping of your files even if you tell it not to manage the library. So adding a network file path is going to be dependent on the speed of your network to your network file share. Now the good news is, if your network drive is a Mac booting drive that has the same AppleID assigned to it, or has one on Family File Sharing, you can see the photos on another boot drive on a different computer by sharing the library on the external network drive. Though you won't be able to make changes to the library unless you remote into the library's home location with Screen Sharing or Anydesk.