Recently I noticed that they now require a secure connection with the same incoming server's credentials, and I also had to update the SMTP address. Here is the configuration for Mail at Settings... → Accounts → Server Settings (header) → Outgoing Mail Server (SMTP) that worked for my POP rr email account: (create a separate outgoing mail server "account" configuration for each unique email account since some of the fields are account-specific)
- uncheck "Automatically manage connection settings"
- User Name: your FULL email address
- Password: the same password as your incoming mail server from above
- Host Name: smtp-server.??.rr.com (where ?? matches that of your email address)
- Port: 25
- CHECK "use TLS/SSL"
- Authentication: Password
And don't forget to press save in the bottom right.