Newly selected System Photo Library not uploading old images and video to iCloud
I have a MacBook Air running MacOS Sonoma. I upgraded from 200 GB iCloud to 2TB iCloud, turned an old 1.05 TB library on an external hard drive into my System Photo Library, and then imported everything from my previous System Photo Library located on my internal drive (~170 GB) into my new System Photo Library on my external hard drive, then turned on iCloud Photos Download and Store Originals.
Now, if I take new photos and screenshots on my iPhone, they appear in the MacBook Air’s new System Photo Library, but none of the ~75k old photos and ~7k videos that were present in the 1.05 TB library (but not the ~170 GB library) are being uploaded from the library to iCloud Photos.
What have I done wrong? Is there a way to force all 80k photos and videos to upload to iCloud Photos?
MacBook Air 13″, macOS 14.7