Location Services Not Working on iMac with Ventura 13.7.2

Is the user ( you ) saying, they have logged into the Administrator Account of this computer ?

And then attempted to Turn On Locations Services ( First image >> First Slider ) will to work ?

Restart in Safe Mode. This will perform a Disk Repair, clear cache files and only load Apple Software, extensions and fonts. The boot up will be slow and can take some time - Normal.

Safe Mode will also eliminate Third Party Software, extensions and drivers from loading. It will only load the Minimum amount of Core Apple Processes to allow the the computer to function at a reduced Level of Performance 

Does the issue present in this mode ?

Manage Location Services settings

What " other " things is System Settings / Preferences can not be turned ON or turned OFF ?