I agree with Allan, those two VPNs are suspect.
Also, the latest version of DuckDuckGo is 1.179.0, yours appears to be much older and your other VPN was installed in 2024. You are better off without any VPNs but if you insist on using one (two is beyond the pale) you should make sure it is compatible with Tahoe. Even if "turned off," these programs have processes running in the background anyway. Best would be to completely uninstall them with the provider's uninstaller.
Many VPNs have a shady history. One of yours, Private Internet Access, Inc., is a personal VPN service that allows users to connect to multiple locations. In 2018, former Mt. Gox CEO Mark Karpelès was named chief technology officer of PIA's parent company, London Trust Media, despite his criminal conviction for defrauding MtGox and its users.
Why would you entrust your personal and valuable data to flow through servers of a company like that?