In the Finder, select GO and hold the option key down as you did before.
If you want quick reference to it, when you have it open in a window, you will see Library at the to of the Finder Window. Click on the folder on the left side of it and drag it to the sidebar. Then you will just need to click on it in the sidebar in any Finder window.
If you want to unhide it to always show in your User Folder, copy and paste this in terminal and hit return:
chflags nohidden ~/Library
This is your Home Library where all of your setting for applications and system configurations are stored. Each user has their own user account and Library so they can configure the system for their use. Since you said all other users had no problems, the problem has to be within your user account. We just need to be sure that's where you are at, and not in another user Library or the System Library.