HI,
My main Apple ID is based on a email form a Dial-up account I once had. (although I can still fetch mail)
I linked this to an iCloud ID which gives me an @me.com ID as well
I can in fact sign into some places with either name (App Store, iTunes, iCloud itself and Apple Support Dicussions)
However the @me.com name works in Messages as a Valid AIM screen name where as the original email ID does not depsite both being Linked at Apple as the "Same" ID.
Both work as independent emails.
I had an issue when I first did this as Apple Support Communities reverted to the Dial-Up email and I could not change it my Preferences here (I had to use a non Discussions "third party portal" as it were, even though it was still an Apple page to sort that).
Over the years I have created other Apple IDs for various things - mostly ichat testing.
Most of these are @mac.com names as you can still register for these.
I run a web site about iChat and this gave me yet another email and I have used this as my FaceTime ID on Snow Leopard in the FaceTime trial on my MacBook Pro.
My iMac uses the Original Apple ID for both FaceTime and iMessages where as the iCloud part of System Preferences > iCloud uses the iCloud @me.com name to the account.
To say this another way.
At one time you could enter the Apple Site and "register" a Name and that became your ID and did not have to be linked to an email
Later it did need and email and that is what most people use.
Then Apple Launched the .Mac service which issued @mac.com names
This was later replaced by MobileMe and then iCloud.
At the change from @mac.com to MobileMe you could link for email purposes the @mac.com name and the MobileMe @me.com name.
The same has happened with iCloud although you can link this to any type of Apple ID.
This then create two main type of ID:-
Those external emails linked to an account at Apple.
Accounts paid for at Apple giving you one of their endings (@mac.com and @me.com)
If you are not getting anywhere it is most likely that the iMessages server are confused about your account and I would suggest following the link in thr item 6 above.
10:38 PM Thursday; July 26, 2012
Please, if posting Logs, do not post any Log info after the line "Binary Images for iChat"
iMac 2.5Ghz 5i 2011 (Lion 10.7.2)
G4/1GhzDual MDD (Leopard 10.5.8)
MacBookPro 2Gb (Snow Leopard 10.6.8)
Mac OS X (10.6.8),
"Limit the Logs to the Bits above Binary Images." No, Seriously