Thanks, BDAqua. I'm rather an idiot when it comes to system diagnostics. The external drive in question may be kaput - it just makes a whirring sound when I connect it to USB. My Mac doesn't see it - it's not the WD My Book listed under Firewire Info.
Here's what EtreCheck gave me when I queried:
Problem description:
WD external drive won’t mount
EtreCheck version: 2.1.8 (121)
Report generated March 29, 2015 at 1:33:27 PM PDT
Download EtreCheck from http://etresoft.com/etrecheck
Click the [Click for support] links for help with non-Apple products.
Click the [Click for details] links for more information about that line.
Hardware Information: ℹ️
MacBook Pro (Retina, 15-inch, Late 2013) (Technical Specifications)
MacBook Pro - model: MacBookPro11,3
1 2.6 GHz Intel Core i7 CPU: 4-core
16 GB RAM Not upgradeable
BANK 0/DIMM0
8 GB DDR3 1600 MHz ok
BANK 1/DIMM0
8 GB DDR3 1600 MHz ok
Bluetooth: Good - Handoff/Airdrop2 supported
Wireless: en0: 802.11 a/b/g/n/ac
Battery Health: Normal - Cycle count 69
Video Information: ℹ️
Intel Iris Pro
NVIDIA GeForce GT 750M - VRAM: 2048 MB
Color LCD spdisplays_2880x1800Retina
System Software: ℹ️
OS X 10.10.2 (14C1514) - Time since boot: 18:41:12
Disk Information: ℹ️
APPLE SSD SM0512F disk0 : (500.28 GB)
EFI (disk0s1) <not mounted> : 210 MB
Recovery HD (disk0s3) <not mounted> [Recovery]: 650 MB
Macintosh HD (disk1) / : 499.05 GB (369.31 GB free)
Core Storage: disk0s2 499.42 GB Online
USB Information: ℹ️
Apple Internal Memory Card Reader
Apple Inc. Apple Internal Keyboard / Trackpad
Apple Inc. BRCM20702 Hub
Apple Inc. Bluetooth USB Host Controller
Firewire Information: ℹ️
WD My Book 800mbit - 800mbit max
EFI (disk2s1) <not mounted> : 210 MB
My Book Two (disk2s2) /Volumes/My Book Two : 2.00 TB (315.52 GB free)
Thunderbolt Information: ℹ️
Apple Inc. thunderbolt_bus
Apple Inc. Thunderbolt to FireWire Adapter
Gatekeeper: ℹ️
Mac App Store and identified developers
Launch Agents: ℹ️
[not loaded] com.adobe.AAM.Updater-1.0.plist [Click for support]
[loaded] com.google.keystone.agent.plist [Click for support]
Launch Daemons: ℹ️
[loaded] com.adobe.fpsaud.plist [Click for support]
[loaded] com.adobe.SwitchBoard.plist [Click for support]
[loaded] com.google.keystone.daemon.plist [Click for support]
[loaded] com.microsoft.office.licensing.helper.plist [Click for support]
User Launch Agents: ℹ️
[loaded] com.adobe.AAM.Updater-1.0.plist [Click for support]
[loaded] com.adobe.ARM.[...].plist [Click for support]
[loaded] com.adobe.ARM.[...].plist [Click for support]
[running] com.amazon.music.plist [Click for support]
User Login Items: ℹ️
iTunesHelper Application (/Applications/iTunes.app/Contents/MacOS/iTunesHelper.app)
Google Chrome Application Hidden (/Applications/Google Chrome.app)
Google Drive Application (/Applications/Google Drive.app)
Amazon Cloud Drive Application (/Applications/Amazon Cloud Drive.app)
Music Manager Application Hidden (/Users/[redacted]/Library/PreferencePanes/MusicManager.prefPane/Contents/Helpe rs/MusicManagerHelper.app)
WDDriveUtilityHelper Application (/Applications/WD Drive Utilities.app/Contents/WDDriveUtilityHelper.app)
Internet Plug-ins: ℹ️
AdobeExManDetect: Version: AdobeExManDetect 1.1.0.0 - SDK 10.7 [Click for support]
FlashPlayer-10.6: Version: 17.0.0.134 - SDK 10.6 [Click for support]
Default Browser: Version: 600 - SDK 10.10
AdobePDFViewerNPAPI: Version: 11.0.10 - SDK 10.6 [Click for support]
AdobePDFViewer: Version: 11.0.10 - SDK 10.6 [Click for support]
Flash Player: Version: 17.0.0.134 - SDK 10.6 [Click for support]
QuickTime Plugin: Version: 7.7.3
SharePointBrowserPlugin: Version: 14.4.4 - SDK 10.6 [Click for support]
JavaAppletPlugin: Version: 15.0.0 - SDK 10.10 Check version
User internet Plug-ins: ℹ️
Google Earth Web Plug-in: Version: 7.1 [Click for support]
Safari Extensions: ℹ️
Pin It Button
3rd Party Preference Panes: ℹ️
Flash Player [Click for support]
MusicManager [Click for support]
Time Machine: ℹ️
Auto backup: YES
Volumes being backed up:
Macintosh HD: Disk size: 499.05 GB Disk used: 129.74 GB
Destinations:
My Book Two [Local]
Total size: 2.00 TB
Total number of backups: 5
Oldest backup: 2014-11-22 19:45:16 +0000
Last backup: 2015-03-29 20:10:35 +0000
Size of backup disk: Excellent
Backup size 2.00 TB > (Disk size 499.05 GB X 3)
Top Processes by CPU: ℹ️
27% Google Chrome
3% Finder
3% WindowServer
0% com.apple.WebKit.WebContent
0% fontd
Top Processes by Memory: ℹ️
258 MB Google Chrome
241 MB firefox
206 MB Finder
206 MB Google Chrome Helper
155 MB com.apple.WebKit.WebContent
Virtual Memory Information: ℹ️
7.86 GB Free RAM
5.20 GB Active RAM
568 MB Inactive RAM
1.66 GB Wired RAM
39.49 GB Page-ins
188 KB Page-outs
Diagnostics Information: ℹ️
Mar 29, 2015, 01:29:51 PM /Users/[redacted]/Library/Logs/DiagnosticReports/com.apple.preferences.extensio ns.remoteservice_2015-03-29-132951_[redacted].crash
Mar 28, 2015, 07:03:23 PM /Library/Logs/DiagnosticReports/Google Chrome_2015-03-28-190323_[redacted].cpu_resource.diag [Click for details]
Mar 28, 2015, 06:52:03 PM Self test - passed