The new Maverick update form Apple 10.9.2 has fixed my problem on 17" 2010 MBP. 🙂🙂
What I had to do to fix it.
Install the 10.9.2 update.
Used kext drop app took to install the Kext files that worked for my express card in Mountain Lion (if you have the original installer for the express card then use that).
Inserted my express card and it worked !
Hope it works for you.
I have the generic high spped usb3 express card that now transfers the data at over 100 Megs per second !!!!!! on my usb3 external drive. Just copied the Maveric 5GB install file in under a minute. So pleased Apple have fixed this express card issue.
What I used
kext drop app
CalDigitFastIO.kext
CalDigitUSBxHCI.kext
that worked with my AKE express usb3 BC628 card. Make sure you get the slim version that fits in the mac express slot not the one that fits in a pc slot. I have the AKE as I purchased few years ago, can't see theat company and paid about £10 (thought it was worth a punt as I have windows 7 and mac on the MBP). I had to flash the bios on that card using my PC partition when I first got it.
They have similar one on Amazon uk, which peopel say works.
GMYLE(TM) ExpressCard 34/54 to USB3.0 Express Card Adapter Dual Ports Windows 7/XP/Vista
Best of luck.