As an update for those running ≥10.11, this OS is 'rootless' and trying to copy or save the DVDPlayback file will not be allowed under normal settings.
2 options - disable the rootless protection OR copy the file manually:
Disable (and re-enable) instructions: http://osxdaily.com/2015/10/05/disable-rootless-system-integrity-protection-mac- os-x/
Save the edited DVDPlayback file and then copy the edited file manually to its proper location using terminal:
1) After you have completed editing the DVDPlayback file in your HexEditor by replacing all 4 instances of 'Internal' with 'External', save the edited DVDPlayback file (no file extension) to the root folder of your system hard drive.
2) Reboot the computer to the 'Recovery' drive. Can be done by rebooting and holding down the 'option' key until all of your bootable drives appear. Select the 'Recovery' drive.
3) In the Utilities menu of the Recovery drive, open Terminal and use the following command:
#Systemdrive is the name of your hard drive on which you saved the edited DVDPlayback file
cp -f /Volumes/Systemdrive/DVDPlayback /System/Library/Frameworks/DVDPlayback.framework/Versions/A/DVDPlayback
4) Run the First Aid command in the Disk Utility app on the Recovery Drive, then reset your computer and watch a DVD.