My new mac pro did this once a few months ago, though up until a week ago it has been behaving fine, sleeping/waking many times a day.
Now it has failed to wake twice in a week (sleeping and waking many times in between the two failures).
Both failures were after sleeping overnight. No external drives were connected at the time.
The log of this mornings failure.
02/11/2014 06:27:19.446 powerd[26]: com.apple.message.domain: com.apple.sleep.failure
com.apple.message.signature: Capability Failure
com.apple.message.summarize: YES
SenderMachUUID: 1F97CC0A-F1D6-3A56-BA08-E644AD7CCF82
This is the 'powerd' history before the sleep failure. I always wake it on a single click of the mouse.
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01/11/2014 14:31:36.393 powerd[26]: com.apple.message.domain: com.apple.darkwake.capable
com.apple.message.hardware_support: smc_without_platform
com.apple.message.settings: ac
SenderMachUUID: 1F97CC0A-F1D6-3A56-BA08-E644AD7CCF82
01/11/2014 16:02:25.275 powerd[26]: com.apple.message.domain: com.apple.iokit.wakereasons
com.apple.message.signature: Maintenance
com.apple.message.signature2: unsupported
com.apple.message.signature3: Maintenance
com.apple.message.summarize: YES
SenderMachUUID: 1F97CC0A-F1D6-3A56-BA08-E644AD7CCF82
01/11/2014 17:03:33.271 powerd[26]: com.apple.message.domain: com.apple.iokit.wakereasons
com.apple.message.signature: Maintenance
com.apple.message.signature2: unsupported
com.apple.message.signature3: Maintenance
com.apple.message.summarize: YES
SenderMachUUID: 1F97CC0A-F1D6-3A56-BA08-E644AD7CCF82
01/11/2014 17:42:52.268 powerd[26]: com.apple.message.domain: com.apple.iokit.wakereasons
com.apple.message.signature2: unsupported
com.apple.message.summarize: YES
SenderMachUUID: 1F97CC0A-F1D6-3A56-BA08-E644AD7CCF82
01/11/2014 18:02:30.264 powerd[26]: com.apple.message.domain: com.apple.iokit.wakereasons
com.apple.message.signature: SleepTimer
com.apple.message.signature2: unsupported
com.apple.message.signature3: SleepTimer
com.apple.message.summarize: YES
SenderMachUUID: 1F97CC0A-F1D6-3A56-BA08-E644AD7CCF82
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