There is an old error in Time Machine software with an apostrophe in the machine name 'Bevan's iMac' which used to cause problems. If you have the old TM drive, you can see if this file/directory exists in the backup.
/System/Library/PrivateFrameworks/WebKit2.framework/Versions/A/XPCServices/com.a pple.WebKit.Plugin.64.xpc
Was your iMac's name different when it last worked correctly? You can try changing your machine name and check if the backup generates the same error. If this is a new drive that has never had a successful backup, you can also initialize the disk and set it up as a backup disk.
In my case, I do not have an apostrophe in my machine name, because I have had issues in the past with the machine name. I make all my machine names with the dash character, if needed, and without any spaces.
From what you have posted I cannot discern if the 'Macintos h HD' has a hidden control character or it is just the way it has been formatted.
Also error -48 says there is a duplicate filename when a rename (mv) is attempted. The second error, -8062, is related to the previous error because the parent directory that contains the file does not exist due to error -48. See the output of ls -lR following the two error codes.
macerror -48
Mac OS error -48 (dupFNErr): duplicate filename (rename)
macerror -8062
Unknown error (-8062) at /usr/bin/macerror5.16 line 40, <DATA> line 1.
ls -lR /System/Library/PrivateFrameworks/WebKit2.framework/Versions/A/XPCServices/com. apple.WebKit.Plugin.64.xpc/Contents/
total 0
-rw-r--r-- 1 root wheel 2046 May 16 08:43 Info.plist
drwxr-xr-x 3 root wheel 102 May 16 08:44 MacOS
drwxr-xr-x 3 root wheel 102 May 16 08:44 _CodeSignature
-rw-r--r-- 1 root wheel 463 May 16 08:43 version.plist
/System/Library/PrivateFrameworks/WebKit2.framework/Versions/A/XPCServices/com.a pple.WebKit.Plugin.64.xpc/Contents//MacOS:
total 16
-rwxr-xr-x 1 root wheel 45024 May 16 08:43 com.apple.WebKit.Plugin.64
/System/Library/PrivateFrameworks/WebKit2.framework/Versions/A/XPCServices/com.a pple.WebKit.Plugin.64.xpc/Contents//_CodeSignature:
total 0
-rw-r--r-- 1 root wheel 3928 May 16 08:43 CodeResources