@Loner T
The USB thumb drive is USB V2.0.
I've downloaded the ISO 3 times using the mediacreationtool.exe and checked the byte count (I didn't do a checksum because I didn't know what to compare it to on OS X coming from a Win 7 system). I tried transfering it between systems using Gb Ethernet, a USB thumb drive and WiFi. In any case, the file size was identical between source and destination 2,662,137,856 bytes (2.66 GB on disk), not very accurate I know.
I can open each ISO on the Mac using the Finder with no problems. I looked around for any text that would identify this as a 64bit vs a 32bit version of Windows. Nothing.
Thanks Loner T! I'll try the mds5 hash too.
I spent an hour on the phone with Apple tech support. Conclusion: "Call Microsoft." They said, "You obviously have the wrong .ISO file." They said that transferring it between systems via Ethernet was prone to errors for large file sizes and said to do it via a USB thumb drive. I did the transfer with a thumb drive with the same result in BCA. I copied it again with the same result. That's when they said to call MS.
I spent two hours on the phone with Microsoft (OMG were they bad, 2nd worst tech support experience in about 500 hours of experience wasting my life on tech support calls for Windows) Conclusion: "Call Apple, only Apple would know if you have the right version of Windows to install on their systems." When I pressed to determine whether I'd purchased a full version vs. an upgrade and whether there was any way to determine if it was 64bit and whether I'd used an official download procedure, they said they have no idea and transferred my, twice. Finally, the answers were: yes you have the right file, yes its 64 bit, and yes mediacreationtool.exe is THE official method to get the .iso file, then they said to call Apple.
Third hour on phone with Microsoft, this time to the Microsoft Store tech Support, they TRIED to give me a refund, but they couldn't figure out how to do it. There was a language barrier. They said to login to the mswos.com site and click the submit button. No matter how many times I told them there was no submit button, they kept telling me to click it.
Regarding their refund process at the msows.com website...
MS: "Do you see the button now?"
Me: "No"
MS:"OK, now click it"
Me: "There is no button to click!"
MS:"OK, do you see it? Now click it!"
repeat for 30 minutes
She took remote control of the system, 15 minutes later,
MS:"Apparently, there is no button."
My plan is to buy a shrink-wrapped, full version of Windows 8.1 with DVD and create an ISO from that. I may have tossed all my systems out the window by then however... My wife is questioning my wisdom that the iMac is better than Windows and requires less tweaking and has fewer support problems because I've been on the phone to support for a total of 7 hours since I received it to replace the older iMac. Please no comments on this, things will devolve into a flame war. They're both good systems in their own special way...