HI,
I have several @mac.com addresses that I still use as Valid AIM Names (but not as iMessages IDs)
Apple launched the .Mac service and for this you got your @mac.com ID
This was a paid for account.
However as Trail account the name was still valid with AIM as a Screen Names as were lapsed accounts.
When Apple Introduced MobileMe the .Mac service ended but those with @mac.com email accounts (paid for ones) could elect to link the email to their new @me.com ID.
This would give them two valid AIM Screen Names.
When iCloud came along those with an @me.com ID could elect that this was their iCloud ID.
This gave the appearance that the ID was "moved" from the MobileMe server to the iCloud server.
Later Apple issued @icloud.com IDs to iCloud users.
Overall this could mean that people have what looks like three Apple IDs (Albeit linked to one account) that cross over the different types of email ID that have been used.
If they have elected to, all will work as the same Email account.
It is only as iMessages accounts and as AIM Screen Names that they still act independently.
That said it is not always clear cut with iMessages.
I have my Apple ID deliberately set up with a different email so that the emails from the Apple Support Communities don't go to the Dial-up account that was and is my Original Apple ID.
I also see the big notice to make them the same.
I have found it difficult (impossible to change it to either the @me.com or the later @iCloud.com O got when I linked the account to iCloud.
There is also this Doc from Apple OS X: Using me.com or mac.com IDs with AIM in iChat requires OS X v10.7.2 or later
This refers to using those older IDs with the AIM Service is older versions of the iChat app and the earliest version of iChat 6.
Basically in Messages the AIM login is also linked to an Apple Login so that this process allows the Apple end to verify that you are using Messages and the AIM Server so that the AIM servers can "read" the password.
iCloud IDs are like this and have never worked in iChat 5 or earlier.
This Doc is generated by the AIM end wanting more security.
Also I have tried using an @mac.com ID as an iMessages ID but it does seem that it need to be linked to iCloud.
At present you can still have Apple IDs that are not iCloud linked - whilst getting a new Apple ID does seem to make them synonymous.
I hope you have some luck with the Apple Support team on this.
8:26 pm Friday; September 12, 2014
iMac 2.5Ghz i5 2011 (Mavericks 10.9)
G4/1GhzDual MDD (Leopard 10.5.8)
MacBookPro 2Gb (Snow Leopard 10.6.8)
Mac OS X (10.6.8),
Couple of iPhones and an iPad