"any other suggestions for getting to that path? i attempt to go there and there is no extensions within library, systems...having some serious issues trying to restore my new iphone 6!
running a 32 bit macbook with 10.6.8…."
ASLL001, I'm wondering if you are looking in the wrong library. Try this….go to the GO menu in your menu bar, scroll down to Computer, select your hard drive ( if you didn't rename it, it is probably Macintosh HD), then select System, then Library, then Extensions, then look for that file. If it is NOT there, that could still be a problem because I believe it is needed to connect your iPhone via USB. If it is not there, I'd still try downloading iTunes from the web, and reinstalling it. I should mention, I keep my iTunes folder in the SHARED folder on my hard drive rather than in my USER folder so all users have access to it.
I'm running 10.8.5
If you just got a new iPhone 6, you have free tech support for 90 days so you might try calling 1 (800) MYAPPLE. If you don't feel like you are getting any answers with the person who helps you, ask for a senior tech advisor. I often find I need to do that because I often find i know more than the people initially answering the phones.
Good luck!