You are not trying to create a new MBR, but if you look at the Gdisk menu, the following steps will let you change the partition type of a specific partition.
sudo gdisk /dev/disk0
GPT fdisk (gdisk) version 0.8.10
Warning: Devices opened with shared lock will not have their
partition table automatically reloaded!
Partition table scan:
MBR: hybrid
BSD: not present
APM: not present
GPT: present
Found valid GPT with hybrid MBR; using GPT.
Command (? for help): t
Partition number (1-4): 2
Current type is 'Apple Core Storage'
Hex code or GUID (L to show codes, Enter = AF00): AF05
Changed type of partition to 'Apple Core Storage'
Command (? for help): p
Disk /dev/disk0: 500118192 sectors, 238.5 GiB
Logical sector size: 512 bytes
Disk identifier (GUID): 22749ACF-207D-458E-B255-5DF02C39DC2D
Partition table holds up to 128 entries
First usable sector is 34, last usable sector is 500118158
Partitions will be aligned on 8-sector boundaries
Total free space is 1325 sectors (662.5 KiB)
Number Start (sector) End (sector) Size Code Name
1 40 409639 200.0 MiB EF00 EFI System Partition
2 409640 250801735 119.4 GiB AF05 OSY-MBP13
3 250801736 252071271 619.9 MiB AB00 Recovery HD
4 252071936 500117503 118.3 GiB 0700 BOOTCAMP