Hi Derek,
Times (ie.time of day values) entered into a Numbers document ALWAYS include a date part as well as a time part. If you enter only a time of day value, Numbers assigns the current date to the date part.
According to your description, each of the work periods entered will begin and end on the same day (ie. NONE will begin before midnight and end after midnight). Provided that is ALWAYS true, AND you always enter the start time during the same calendar day as you enter the end time, you can skip entering the date as part of that time.
Subtracting the start time from the end time will give you a duration value corresponding to the time duration worked in hours and minutes.
DUR2HOURS converts the duration value to a number representing the number of hours, including a decimal part representing the fraction of an hour.
Multiplying by a number representing the hourly pay rate gives the gross pay for that work period.

Times in columns B (start) and C (end) are entered as shown, or as 24 hour clock values (15:00, 16:25 and 13:50 respectively for the 'end' times). Both columns are formatted as Time and Date, with Time set to either the 12 hour clock as shown or the 24 hour clock, and Date set to 'none'.
Column D contains the formula =C-B and is formatted to show duration in the manner shown above.
Column E contains the hourly rate for each worker, formatted as a number.
Column F contains the formula =D*E, formatted as currency, with the default 2 decimal places.
Further details will depend on a more detailed question regarding the results you want.
Regards,
Barry