It is possible to use a Windows machine like that to create bootable Mac floppies from certain Disk Copy disk images. The Network Access 7.5 disk, which can be used as a boot floppy, is one example:
The special procedure requires the use of an appropriate version of Aladdin/StuffIt Expander for Windows in order to decode the .bin (MacBinary) and decompress an intermediate file to begin with.
The stuffit-expander-10-windows.uu from the site below could possibly be OK (see the abstracts text file for details; the uuencode must be decoded before the freeware utility can be installed on a PC): http://archive.info-mac.org/_Compress_&_Translate/
A disk-image utility for PC will also be needed. For example, the shareware utility WinImage 6.10.
Install the programs on the PC.
Prepare an empty PC-formatted 1.44 MB (HD) diskette through the FORMAT A: command in DOS or via the "full" formatting command under Windows. This is important.
Download the Network Access Disk 7.5 .bin file.
http://download.info.apple.com/Apple_Support_Area/Apple_Software_Updates/English -North_American/Macintosh/Utilities/Network_Access_Disk_7.5.sea.bin
The Windows operating system may truncate the file name. Drag this downloaded file (as it is) onto/into Aladdin/StuffIt Expander. Aladdin/StuffIt Expander should decode the file into an archive (document) called Network Access Disk 7.5, and automatically decompress the latter into a Network Access folder.
Inside the Network Access folder you will find a Read Me document and a file called Network Access.image.
Insert the empty PC-formatted diskette into the PC's floppy drive.
If WinImage is used, drag the Network Access.image onto the program icon. In the WinImage application window, select Write disk (from the Disk menu) or click on the Write disk icon. When the operation is completed, immediately eject the diskette. In order to make this work, it may become necessary to (temporarily) switch off any active anti-virus software.
1.44 MB is not much, so you should really have a working hard drive in the Classic. Floppy disks are best for startup purposes, as tools disks, and for transfers and backup.