What I did:
DISKPART list volumes
VOLUME 0 C BOOTCAMP NTFS Partition 121 GB Healthy
VOLUME 1 D WININNSTALL FAT32 Removable 7663MB Healthy
select volume 0;
attributes volume clear readonly;
OUTPUT: Volume attributes cleared successfully.
then I did the copies.
To c:\Windows\system32 it was OK.
To c:\Windows\System32\boot it was NOT OK (The process cannot access the file because it is being used by another process).
Note that previously there was no copy error.
update: I navigated to the boot folder then deleted winload.exe (it worked....strange!)
then I copied the specified file into there.
then I tried to boot into windows but it failed (System32\winload.exe is the error file)
result of the MD5 checking:
./Windows/System32/Boot/winload.exe
MD5(./Windows/System32/Boot/winload.exe)= 7eaf2f0acfee4c463f69bfb7f96c0446
./Windows/System32/winload.exe
MD5(./Windows/System32/winload.exe)= 7eaf2f0acfee4c463f69bfb7f96c0446
./Windows/WinSxS/amd64_microsoft-windows-b..ment-windows-minwin_31bf3856ad364e35 _10.0.10240.16384_none_57ec180996abd934/winload.exe
MD5(./Windows/WinSxS/amd64_microsoft-windows-b..ment-windows-minwin_31bf3856ad36 4e35_10.0.10240.16384_none_57ec180996abd934/winload.exe)= 0ba0c50d2e6ec5658713b453389659b9
./Windows/WinSxS/amd64_microsoft-windows-b..ment-windows-minwin_31bf3856ad364e35 _10.0.10240.16405_none_57edd07996aa22aa/winload.exe
MD5(./Windows/WinSxS/amd64_microsoft-windows-b..ment-windows-minwin_31bf3856ad36 4e35_10.0.10240.16405_none_57edd07996aa22aa/winload.exe)= 6e8b85a2274d2a7898ad88c844e87ef4
./Windows/WinSxS/amd64_microsoft-windows-b..vironment-os-loader_31bf3856ad364e35 _10.0.10240.16384_none_63272be107542aec/winload.exe
MD5(./Windows/WinSxS/amd64_microsoft-windows-b..vironment-os-loader_31bf3856ad36 4e35_10.0.10240.16384_none_63272be107542aec/winload.exe)= 0ba0c50d2e6ec5658713b453389659b9
On the installation pendrive:
MD5(./backup/winload.exe)= 7eaf2f0acfee4c463f69bfb7f96c0446
So it seems that it stucked with the backed up version.