As Ian has already noted, canned air runs a real risk of blowing gunk back into the chassis, and if you tilt the can you can send a shot of the propellent in as well. Worst case, the gunk could be slightly conductive and cause shorting within the chassis. If you're intent on using canned air, keep the car upright, aim it at the sides of the rear exhaust vents at an angle towards the rear, and do it with the eMac turned on so that the fan is running and providing some airflow pressure outwards.