As it stands now, you have not assigned a separate name to the 5 GHz band on your AirPort router, so wireless clients will connect to either 2.4 GHz or 5 GHz depending on their own capabilities and distance in relation to the router.
Unless the Apple TV is located in the same room as the AirPort router, or you have close to a line-of-sight relationship between the Apple TV and the AirPort router, the Apple TV will likely connect to the stronger 2.4 GHz signal, even though the 5 GHz "ac" signal might be a faster connection.
Open AirPort Utility
Hold down the option key on your Mac while you double click on the picture of the AirPort router
Wireless Clients will appear
Click on the arrow next to each connected wireless client for more information about that device
Post back with the info that you see displayed for the Apple TV connection