Here is a troubleshooting support document you can try. Get help if you can't make or receive FaceTime calls on your iPhone, iPad, or iPod touch - Apple Support
Are you on wi-fi, or does your carrier support FaceTime over cellular? So even if you open FaceTime, then search for his name there, it does not come up? If you open FaceTime after he has called you on FaceTime, which you said he could do, does it list him and his contact information there? If you tap on it to call him from there what happens?