Good evening sqzdog,
Welcome to the Apple Support Communities!
I understand you are trying to synchronize your iCloud Photo Library with your PC. The resource below explains that once this is set up, new photos and videos will automatically download to your PC. You will need to download existing photos manually. I've highlighted some key information here for you. Click on the links for complete details.
Get help with iCloud Photos on your Windows PC
After you turn on iCloud Photo Library on all of your devices, any new photos and videos you add to your library will automatically download to your PC. You can also download your photos and videos by year.
Set up and use iCloud Photo Library on your Windows PC
- Download iCloud for Windows.
- Open iCloud for Windows.
- Next to Photos, click Options.
- Select iCloud Photo Library.
- Click Done, then click Apply.
- Turn on iCloud Photo Library on all of your Apple devices.
Download your photos and videos from iCloud Photo Library
New photos and videos you add to iCloud Photo Library will automatically download to your PC. You can also download your collection by year when you follow these steps:
- Open a File Explorer window.
- Under Favorites, click iCloud Photos.
- Click Download photos and videos.
- Choose the photos and videos you want to download and click Download.
Your photos and videos download to the location you set in iCloud Photos Options.
Take care.