The library.xml file is not used by iTunes.
It is only written by iTunes for use by other apps.
Yeah, I actually learned that in this (or that other thread last week! I figured I would do it anyway since it was so fragged. Question though...when does iT write and update that XML file? Is it when you quit iT?
I'll probably use Tech Tools (which I got with my extended applecare warranty) to defrag my whole drive.
I'm realizing that while reading up on all those other links that Rod passed along, but thanks for the confirmation. Man you can really fall down the rabbit hole trying to get to the bottom of these tech questions!
I actually purchased iDefrag and I am doing an "on-line" defragmentation of my iTunes Library file right now. I have to say, it's taking a long time. It's been over 15 minutes already and over half of the time has been spent "allowing disc to cool". I need to look into that.
As for Tech Tools, I never figured out how to use it properly anyway. When I would boot-up from the CD ROM it wouldn't start for over 10 minutes. I'm reading up on that as well.
Anyway, I'll report on how defragging the Library file affects things...if at all.