Mac Pro 5,1 diagnostic light on- won't boot
I've had a 2012 Mac Pro A1289 3.33 GHz 6 core purchased refurb from Apple since 2014 that's been trouble free until now with the configuration it's had for most of it's years: 3 x 4 GB ram, a professionally flashed GTX 780, and 2 250GB Samsung 850 EVO's on an Apricorn Velocity Duox2 PCIe card in the second X4 slot from the top running OSX 10.11.6 and Windows 7 Pro.
Recently I took the PCI card out to put the SSD's into the normal HDD bays to re-install windows, once for Win10, then again after deciding to go back to Win7. After putting the PCI card back in the 2nd time the machine would not boot but only power on for less than a second then shut down (relay click heard), with a solid red LED diagnostic light at the upper LH corner of the backplane board near the front of the case labelled OVTEMP CPUA (the top most of 4 lights) that remains on. If I press the button labelled DIAG LED just below it I get a green light at the bottom of the same 4 LED's marked 5V STBY.
The machine was running fine only minutes before in both OS's when finishing up my OS install. Am wondering if I bumped or caused something while working only in the PCIe area. I did mis-seat the PCI card the second time and after re-seating it properly have since taken everything out and inspected for bent pins or anything loose or out of place. Still get the same symptoms after trying to boot with only the video card, normal and proven boot HDD, and wired Apple keyboard and mouse in place. Need some advice related to diagnosis, further testing, and fix.