Sorry for the late reply gentlemen, but I've looked at your screengrabs that you provided and compared them to what's on my phone. These were all taken from my iPhone 8 Plus.
Riazhosain:
Check the attached screenshots out from my phone:

If your carrier was supported, you would see this screen in your Settings Menu. The setting "Calls on Other Devices" appears because I also have a 6S Plus as well (that I retain and just updated, this phone gets updated once every 2-3 weeks, in reference to the 6S Plus, the 8 Plus gets updates as needed which is everyday). If you do not have multiple devices on you Apple ID account you will not see this option.

This screen here, is in reference to your 2nd and 3rd screenshots. If your carrier was supported, you would not be seeing the second and third screenshots. All the APN information (including MMS, LTE and of the like) are automatically put in for you. You cannot edit this out. From what you provided to me, and the forum, it's more than likely your carrier has to be certified for LTE from Apple. I would say 98%. That's why you see the pop up message on your iPhone with the second screenshot. That would be the main clue.
Before my carrier was certified, I would get the same screens you did, but once IMT-E came online (Band 7 LTE), I would still be able to edit out the APN settings, but still access LTE (in other words I wasn't blocked from accessing it on a 6S Plus). But as mentioned before once Freedom gained the ability to sell the iPhone (which means the network got certified by Apple), 4 days before the iPhone went live for preorders and Freedom Mobile locations, the iPhones registered with the network got a Carrier Update. This removed the ability to manually edit out the APN settings. This would be another clue that your provider has not been certified by Apple. But Freedom didn't block the iPhones on the network before they were approved by Apple.
By default, if the phone is set to LTE, it will default to 3G for a number of reasons. I've had that happen with my phone. If VoLTE is not active on the provider you are on, it'll drop to 3G for the phone call. It does this with my device, because Freedom is implementing VoLTE (Possibly on Band 13) and VoWiFi (which eliminates pretty much everything in the book in regards to reception with the exception of a few things). This is not cause for alarm however.
You have a 4G SIM. That is good.
Crimsonvspurple:
"And the operators are saying it is not working because there is a block from Apple's side on using LTE in Bangladesh".
Which still gets me, but from the second screenshot that riazhosain posted, it's more than likely that to be the case. Apple is brutal about LTE requirements.
"I tested things by literally standing in front of GP's head office as have some other people. All works except iphone".
Which is what I wanted you to do. Freedom's head offices are in Toronto, Ontario, about 30 minutes away from where I live. If LTE didn't work on my phone when they rolled out LTE I'd be doing the exact same thing for (insert word here) and giggles.
"GP's 4G coverage is limited at this moment even though they are the largest operator. But other carrier has almost 100% coverage (by population; not by ground-area). Other carriers are not far behind".
The 3 major cellphone providers here (Canada) are Rogers, Telus and Bell. Freedom Mobile is only in parts of Ontario, British Columbia and Alberta. Roaming is covered by those three and AT&T in the USA. Smaller providers include BellMTS, SaskTel, Videotron and Eastlink. All of them are certified by Apple for LTE. But as I said before I believe that the technology will mature with time, and it will. Freedom Mobile's coverage is limited, and so are the 4 smaller providers, but they are still certified by Apple for LTE.
I hope this clears things up for you. I still have no quarrel with both of you.