Does it show on the account's purchase history : See your purchase history in the App Store or iTunes Store - Apple Support ?
If not the charges may just be : About payment card authorisation holds in the iTunes Store - Apple Support . If they don't disappear (or there aren't subsequent credits for the amounts) within a week or so you could contact iTunes Support and see what they say : http://www.apple.com/support/itunes/ww or https://www.apple.com/emea/support/itunes/contact.html