These applications will identify and help remove duplicate photos from a Photos Library:
- Duplicate Annihilator for Photos - $7.95
- PhotoSweeper - $9.99 - Demo version available.
- PowerPhotos - $29.95
- Photos Duplicate Cleaner - Free
PowerPhotos is the iPhoto Library Manager version for Photos and is very powerful. Although more expensive I would recommend it as it has more capabilities than the others like the capability to merge Photos libraries or copy photos along with their metadata between libraries.
PhotoSweeper compares bitmaps and/or histograms so it can detect duplicate images even if they have different sizes, file names, sizes and capture dates.
These are the only apps that provided demo versions which could be tested on a test Photos library.
I also use PowerPhotos and PhotoSweeper.