The Library is invisible. The Home folder is the one with a large house icon and your username as the folder name.
Four Ways to Make the Home/Library Folder Visible
A. This method will make the folder visible permanently. Open the Terminal application in the Utilities' folder and paste the following red colored command line at the command prompt: chflags nohidden ~/Library then press RETURN.
B. Click on the Desktop, press the Option (⌥) key, select Library from the Finder's Go menu.
C. Select Go To Folder from the Finder's Go menu. Paste the following in the path field: ~/Library and click on the Go button.
D. In Sierra activate the Finder, press COMMAND-J, set Finder display to Icon view if it is in some other view mode, select your Home folder from the sidebar, check the box labeled, "Show Library Folder.