Hi ialreadydidthis,
In Numbers, format the times (Column A) with Format Panel > Cell > Data Format > Date & Time > Date: None and Time: as 24 hour clock (hours:minutes:seconds)*.

Formula in column B (and Fill Down)
= DURATION(,,TIMEVALUE(A2)×24)
From the Function Browser,
The TIMEVALUE function returns the time as a decimal fraction of a 24-hour day for a given date/time valueor time string.
Multiply by 24 to get a Duration.
Note the leading commas that tell Numbers to leave out Weeks and Days in the DURATION part of the formula.
Column B is formatted as:

*Further testing shows that it does not matter how Column A is formatted, so long as the times are valid. This method calculates the Duration since midnight at the start of a day.

Regards,
Ian.