I've done all that basic stuff on the phone with Apple Support. See below from the system report. It shows that the Mac knows there's 2 daisy chained 5-bigs into one of the thunderbolt ports. But they don't show up in Disk Utilitities, the finder, or on my desktop.
Thunderbolt Bus:
Vendor Name: Apple Inc.
Device Name: iMac
UID: 0x0001000A18166200
Route String: 0
Firmware Version: 22.1
Domain UUID: 49E33E73-ECDA-BF50-A5E6-F1C790542387
Port:
Status: No device connected
Link Status: 0x7
Speed: Up to 10 Gb/s x2
Receptacle: 1
Port Micro Firmware Version: 2.1.3
Port:
Status: Device connected
Link Status: 0x2
Speed: Up to 10 Gb/s x2
Receptacle: 2
Port Micro Firmware Version: 2.1.3
Cable Firmware Version: 1.1.0
5big Thunderbolt 2:
Vendor Name: LaCie
Device Name: 5big Thunderbolt 2
Vendor ID: 0x3
Device ID: 0xA
Device Revision: 0x3
UID: 0x000300005218CF10
Route String: 3
Firmware Version: 24.1
Port (Upstream):
Status: Device connected
Link Status: 0x2
Speed: Up to 10 Gb/s x2
Current Link Width: 0x1
Cable Firmware Version: 1.1.0
Link Controller Firmware Version: 0.14.0
Port:
Status: Device connected
Link Status: 0x2
Speed: Up to 10 Gb/s x2
Current Link Width: 0x1
Cable Firmware Version: 1.1.0
Link Controller Firmware Version: 0.14.0
5big Thunderbolt 2:
Vendor Name: LaCie
Device Name: 5big Thunderbolt 2
Vendor ID: 0x3
Device ID: 0xA
Device Revision: 0x3
UID: 0x0003000052300C10
Route String: 303
Firmware Version: 24.1
Port (Upstream):
Status: Device connected
Link Status: 0x2
Speed: Up to 10 Gb/s x2
Current Link Width: 0x1
Cable Firmware Version: 1.1.0
Link Controller Firmware Version: 0.14.0
Port:
Status: No device connected
Link Status: 0x7
Speed: Up to 10 Gb/s x2
Current Link Width: 0x1
Link Controller Firmware Version: 0.14.0