There are only 15 episodes in https://www.endofthechain.com/podcast-rss/
although there are 20 episodes in https://feeds.blubrry.com/feeds/endofthechain.xml
Since I don't know by what process you are getting your episodes from the blubrry feed to the feed iTunes is using I can't advise on why this isn't happening. The six oldest episodes in the blubrry feed aren't in the endofchain feed, but the latter feed has a recent episode which is not in the blubrry feed.
Neither feed has a 'generator' tag, though I suppose the blubrry feed was created in their process or in Wordpress? As to the other feed, some methods limit the number of episodes in the feed, removing older ones as newer ones are added once the limit is reached, but that doesn't explain why the episode of 2 December isn't in the blubrry feed.
This suggests that you are creating the feeds independently, and that a) you haven't added the Dec 2 episode to the blubrry feed, and b) the endofchain feed is created using a method with a limit of 15 episodes (there is usually a setting somewhere to increase this).