Install MacOS on an external drive and boot from it, so that you can use all the bays while you do this.
Don't make this harder than it is by over-thinking it.
Create a new Mirrored RAID set on the new drive set.
This turns those two drives into one logical mirrored Volume.
Copy or Clone the files from one old Logical Mirrored Volume to a new Logical Mirrored volume.
Now the hard part:
Mirrored RAID is not backup, it merely extends to time to repair after a drive failure to keep a drive failure from always being a data disaster. Mirrored RAID does not protect against multiple failures before you have time to replace a failed drive or accidental deletions or "crazy software",
¿What are you using for backup?