Your router will have a maximum wired speed that is hardware determined: gigabit (1000 Mbps), 100 Mbps, or 10 Mbps. (Or 10000 Mbps if you think you could use that.) Your devices will have a maximum wired speed that is hardware determined. Your cables may be rated for a certain maximum speed (Ethernet Cat 5e or later for gigabit). These are theoretical/marketing numbers, and real world speeds will be a bit lower. Simultaneous active devices on your home network will share the available bandwidth, each getting a part of the total.
Wi-Fi will likewise have an upper limit as determined by the router/WAP. Wi-Fi devices will have their own maximum. This is a bit more complex, as in involves Wi-Fi version compatibility, and number of antennas, and bundling those for a single connection where possible, as well as use of the 2.4 GHz band or 5 GHz band. Sharing the bandwidth with other devices will again lower what is available for each device. It also doesn’t have the neat factor 10 steps. Wireless interference may cause a lower speed.
For your specific setup and real world numbers, you can use speed tester applications.
Speedtest by Ookla (free) (macOS/iOS/tvOS/…) tests the speed that you actually get from the internet/your ISP, on the networked device. This then will include effects of your home network.
LAN speed tester apps (i.e. without internet measurements) may cost a bit, but there are several, if you Google for that. If you are confident that you can get more than 25 Mbps on each device, then you’ll be fine without measurements.