As SSD technology advances (or rather changes) the NAND memory used in SSDs is becoming slower (and also has less endurance, aka number of lifetime writes) so SSD write speeds don't usually end up at the top end of the spectrum. In fact most speed tests reported on these forums many times will show the SSD's write speed to be about half of the read speed.
To make up for the slower NAND memory speed SSDs implement a write cache to make it appear that the SSD is faster, but once this write cache fills up the SSD's speed will drop. How much the speed will drop depends on how the SSD was designed. I have seen some SSDs slow down to 50MB/s and it can take a long time for the write speed to recover. If an SSD overheats the SSD's speed will be throttled until the SSD cools off. The longer the SSD speed test the more likely you will encounter poor write speeds.
Unmount the volumes on the external SSDs (do not eject them since that will cause the drive to lose power) so you can leave the SSDs physically connected and powered on, but they won't have any data transfers or communication with the Mac. With the SSDs unmounted and still connected the SSD still has power so that the SSD's internal maintenance & garbage collections routines have time to work and help the SSD return to normal. After the SSD has been sitting like this for a few hours unplug the SSD and reattach it so you can run another speed test on it.
If the SSDs are nearly full, then that will also cause the SSD write speeds to slow down as the SSD needs to do a lot of behind the scenes work to provide empty blocks for storage (there is a lot of behind the scenes work going on with an SSD).
There may also be a compatibility issue with the newer Samsung SSDs and macOS.
You may want to check the health of the SSDs by running DriveDx. You will need to install a special USB driver so that DriveDx can communicate properly with the USB drives to access their health information. However, some USB drives won't allow the necessary communication to access the health information even when using the special USB driver. Post the reports for your Samsung T7 SSDs here using the "Additional Text" icon which looks like a piece of paper.
Also, maybe Spotlight has decided to index the external drive which can affect the speeds.