I have / had the same problem with Safari freezing the entire start-up process for my 2019 Macbook Pro right after installing Monterey.
I am using Chrome temporarily which helps.
After the start up process completes, I usually open Safari because that is my default browser.
I try to remember to quit Safari before shutting down the computer.
If I forget to quit Safari, on restart, as soon as the dock is operational, I quit Safari and the computer starts up normally. I can then later open Safari and it seems to work for now.
I keep a lot of tabs open and I suspect there may be a conflict with an operation on one of the pages sitting open as it tries to restart some process.
Waiting for a permanent fix.
Thoughts?
Paul