Thank you for taking the time to post the Full Report.
The only major thing, pertaining to this computer issue, that jumps, is running the machine with Multi External Drives at the same time.
Do not know if they were still actively performing some Mission Critical Function and connected at the time the Computer was Shutdown
Experiment with Disconnecting the three drives before Shutting Down. From Cold Boot does the same Error Message appear again ?
Major Issues:
Anything that appears on this list needs immediate attention.
Heavy CPU usage - Some processes are using an unusually high amount of CPU.
Minor Issues:
These issues do not need immediate attention but they may indicate future problems or opportunities for improvement.
Q - Clean up - There are orphan files that could be removed.
A - Refer to below section called " Cleanup "
Q - Unsigned files - There are unsigned software files installed. These files could be old, incompatible, and cause problems. They should be reviewed.
A - Self explanatory. Worth considering updating / upgrading to more current versions for Monterey
Q - System modifications - There are a large number of system modifications running in the background.
A - Anytime the OS is this heavily modified, there are unintended consequences including the issue at hand.
Q - Runaway user process - A user process is using a large percentage of your CPU.
Q - External drives and performance - There are external drives connected that could be affecting performance.
A - This is covered in the pre-amble above
Hardware Information:
MacBook Pro (13-inch, 2020, Four Thunderbolt 3 ports)
MacBook Pro Model: MacBookPro16,2
2 GHz Quad-Core Intel Core i5 (i5-1038NG7) CPU: 4-core
16 GB RAM - Not upgradeable
BANK 0/ChannelA-DIMM0 - 8 GB LPDDR4X 3733
BANK 2/ChannelB-DIMM0 - 8 GB LPDDR4X 3733
Q - disk2 - LaCie P9227 Slim 1.00 TB (Mechanical)
Q - disk3 - WD My Book 1230 4.00 TB
Q - disk4 - WD Elements 25A3 6.00 TB
Network:
Q - iCloud Status: one pending file
Security:
Gatekeeper: App Store and identified developers
System Integrity Protection: Enabled
Q - Antivirus software: Apple and Malwarebytes
A - Malwarebytes is good but does not really need to be running all the time IMHO. It is using Resources that could be better deployed elsewhere
Kernel Extensions:
Q - /Applications/Recoverit.app
[Not Loaded] WondershareDriver.kext - com.wondershare.driver (2.1.3 - SDK 10.14)
A - This one is a user preference but do not personally see any real usage in everyday operations.
Launch Daemons:
Q - [Loaded] com.bombich.ccchelper.plist (Bombich Software, Inc. - installed 2022-01-04)
A - Thumb Up and use it myself. My Go To for years.
Q - [Running] com.malwarebytes.mbam.rtprotection.daemon.plist (Malwarebytes Corporation - installed 2022-05-16)
Clean up:
~/Library/LaunchAgents/com.VoiceFive.AMP.plist
/private/var/folders/62/prwgbzd92nd49pqwrvk3h3980000gn/T/AppTranslocation/569E8BF6-E193-4905-9B90-DEA96D0F640C/d/AMP.app/Contents/MacOS/AMP
Executable not found