It has nothing to do with Apple; if Spotify was using 72% of your battery, that's because Spotify is being very inefficient in how it is using your battery.
As a third party application, they are responsible for the battery usage of their app.
Now you say battery was used even when nothing was running - and that's not true.
Any time your phone is on, it uses battery to remain in contact with your local cell tower or towers, more power when you are connected to 5G than not.
Your iPhone 6S was not 5G-compatible so it did not have 5G radios which use more power than older technologies did.
This isn't an Apple issue, it's all 5G cell phones on the market.
Virtually all phones today are designed with the assumption you will be charging when in the car; you don't have to, but battery life will fall as the radio signal strength needs to be turned up and down as you move away from and jump to a new cell tower.