Thank you for assistance James, unfortunately first aid fails here... going to try 3rd party options.
Thanks. Martin
Running First Aid on “Backups of iMac” (disk6s1)
Checking file system and repairing if necessary and if possible.
Volume is already unmounted.
Performing fsck_apfs -y -x /dev/rdisk6s1
Checking the container superblock.
Checking the checkpoint with transaction ID 65852.
Checking the space manager.
Checking the space manager free queue trees.
Checking the object map.
Checking volume /dev/rdisk6s1.
Checking the APFS volume superblock.
The volume Backups of iMac was formatted by newfs_apfs (1933.80.3) and last modified by apfs_kext (1934.141.2).
Checking the object map.
error: btn: oid (458612122), xid (65852), type (0x40000003), subtype (0xb), flags (0x4) level (1)
error: btn: invalid key order: minkey is less than index 0 (should be equal)
minkey : 04 04 00 00 00 00 00 00 f8 0f 00 00 00 00 00 00
index 0 key : e6 84 02 00 00 00 00 00 ef 0f 00 00 00 00 00 00
index 1 key : f8 84 02 00 00 00 00 00 ef 0f 00 00 00 00 00 00
Checking if the parent's minkey can be updated...
error: btn: oid (387465710), xid (65818), type (0x40000003), subtype (0xb), flags (0x4) level (2)
error: btn: unable to repair minkey
Object map is invalid.
The volume /dev/rdisk6s1 was found to be corrupt and cannot be repaired.
Verifying allocated space.
The volume /dev/rdisk6s1 could not be verified completely.
File system check exit code is 8.
Restoring the original state found as unmounted.
File system verify or repair failed. : (-69845)
Operation failed…