"Video not available"

Can you disclose the show, so that others can try the same?

Does it happen for multiple titles in the Apple TV app?

If it is not a content provider issue …

Something is causing the app to be unable to contact the remote servers.

See if this document has clues that apply to your situation: If you can't watch or stream movies and TV shows in the Apple TV app - Apple Support

“Video not available” may mean no valid reaction from the remote server.

1. Verify that your router doesn’t block Apple’s servers (or its CDN) through a firewall setting.
2. Verify that your router doesn’t block ports that Apple services like to use.
3. Verify that you use a good DNS on your router, like the one from your ISP, which gets updated with all server names that Apple might use.
4. Verify that your TV has the correct date and time and timezone, as Apple may be more strict about that (TLS) than other content providers.

Else

1. Check for TV OS software updates.
2. Check for Apple TV app updates, if not set to do so automatically.
3. Try resetting the Apple TV app.
4. Try deleting and re-installing the Apple TV app, if possible for your device.
5. Try restarting the TV.

Else contact the Apple Support staff for assistance.