How to remove from Apple Pay to PayPal

If you mean remove from your Apple Account balance, see -> Check your Apple Account balance

Check your Apple Account balance – Apple Support (UK)

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If you have an Apple Account balance that you can’t use

You can't redeem or return Apple Gift Cards, App Store & iTunes Gift Cards or unused Apple ID balance for cash, except as required by law. If your jurisdiction allows the refund of redeemed gift balances, you can contact Apple Support to request a refund. 

When you contact Apple, include the following information:

•               Your Apple ID.

•               The refund amount.

•               Your current delivery address.