AirPlay screen mirroring is at 30 fps, 1080p, SDR. That is the protocol, and the screen capture will likely need to be adjusted for that on-the-fly (using the GPU).
Depending on how busy your computer is with other tasks (video playback, gaming, background tasks, etc.), it may not reach that maximum.
In-app AirPlay options (video playback in the TV app, QuickTime Player, or Safari web video) do not involve screen capture and may be more efficient (sending the stream as-is). That will improve the visual quality including frame rate.
Note that most video content is 24 (23.976), 25, or 30 (29.97) fps, regardless of the refresh rate of your TV.
Note that the refresh rate of the TV does not mean that it will accept that number as input frame rate. Unless you have a high end modern TV with FFR gaming optimization, it will probably max out at 60 Hz input through HDMI.
Running the Speedtest app on both the Mac and the Apple TV box should help determine if the network might be a bottleneck or not. If this app sees more than 25 Mbps, then the network has adequate bandwidth in its current configuration (including device distances).
Other network use (other devices and users) may also influence the available home network bandwidth.