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With your account verified, try the following options in order to see if they help fix the issue:
1. Clear the App Store cache
Go to the /username/Library/Caches/com.apple.appstore/ folder and remove the file called "Cache.db." Then relaunch the App Store and try again. You can also try removing the entire "com.apple.appstore" folder from the caches directory and retry the store.
2. Clear Store preferences
As with other applications, corruption in the store's preferences file may result in odd behavior and may affect functions like logging in. Try going to the /username/Library/Preferences/ folder and remove the file called "com.apple.storeagent.plist." Then relaunch the App Store and try again.
3. Fix permissions
If the first two options do not work, try opening Disk Utility and running a full permissions fix on the boot drive. This should ensure all system files are properly accessible by the system and hopefully correct any error with file access that could be contributing to the problem.
4. Reset all warnings in the iTunes Store
Your Mac App Store account should be your iTunes Store account. Open iTunes and enter the iTunes Store. If you are not signed into your account, sign in. Enter your account by clicking your account name in the upper right up the iTunes Store and review your account. At the bottom of your account information page choose +Reset all warnings for buying and downloading+.
5. Run combo updater
Lastly, if the App Store application or a required system component is corrupted, you should be able to overcome the problem by reinstalling it. Go to the Apple Support Downloads page and get the latest combo updater (currently OS X 10.6.6). Restart the system into Safe Mode by holding the Shift key at boot-up, and then run the downloaded installer when in Safe Mode.
Dah•veed
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