Here are some settings for Hotmail, it appears that the "Free Version" which is a POP3 and "Paid for Versions" act differently.
"But now POP3 access is now available to Hotmail users in the United Kingdom, Canada, Australia, France, Japan, Spain, Germany, Italy, and the Netherlands. Microsoft plans to roll out POP3 access to more parts of the world later this year. You can find the settings below:
• POP server: pop3.live.com
• POP server port: 995
• POP SSL required? Yes
• User name: Your Windows Live ID, for example yourname@hotmail.com
• Password: The password you usually use to sign in to Hotmail or Windows Live
• SMTP server: smtp.live.com
• SMTP server port: 25
• SMTP Authentication required? Yes (same as POP3 username and password)
• SMTP SSL required? Yes"
Hope this helps.