I just spoke with an Apple Care tech about the out of synch audio issue in Photo Booth (they had never heard of it at the Apple Store), and he came up with an easy fix:
1. Go up to the upper right corner of your screen and click on the Spotlight icon and type in "audio." The first result should be "Audio MIDI Setup." Choose that.
2. When the Audio Devices window opens, you should see two choices in the left column. Highlight "Built-in Microphone."
3. In the right window, choose the "Input" tab (the other is grayed out).
4. Under "Source: Internal Microphone" you should see two drop-down boxes next to the word "Format." In the left one, choose "44100.0Hz"; in the right, select "2ch-32 bit Float."
That fixed the problem for me. Good luck.